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T 0 v0 "p`   0 W#Click to edit Master subtitle style$ $ T 6z0 #" `` ` 0 @*  T 6 0 #" `` ` 0 B*  T 6|0 #" ``  0 B* T T <v޽h @ ? 3F433___PPT10i. `+D=' = @B +)  0 ((U_-((  &8    Z_ p h V s *"`  7 T [  #  q    B CDEFjJ2 c0@O_oF~o 0Su -<L,\Fl_|x %3*A:MIXYbilyt{'7GWg}wvne[QE9+%4DScst]F,!b1BA QaqjCC.k>N^n~,Qu9 Vs,<L\kz "7K]o )8HXhx  & 6 |F gV Qe 8u      p G    # I3 C S c Gs ` [\@"`N: N W ~   W ~ <B  # W  <B   # W w <B   # W w <B   # WW Xw <B   # W w <B   # W w <B  #  W  w <B  # U W V w <B  #  W w <B  #  W w <B  #  W  <B  # Q W R w <B  #  W w <B  #  W w <B  #  W  w <B  # O W P w <B  #  W w <B  #  W w <B  #  W w <B  # L W M w <B  #  W <B  #  W w <B  #  W w <B  # I W J w <B   #  W w <B ! #  W w <B " # W w <B # # FW Gw <B $ # W w <B % # W w <B & # W  <B ' # CW Dw <B ( # W w <B ) # W w <B * # W w <B + # AW Bw <B , # W w <B - # W w <B . # W w <B / # =W >w <B 0 # }W ~  1 6< )  D-0.2$G  2 6xv    D-0.1$G  3 6    C0.0$G  4 6  j  C0.1$G  5 6x     C0.2$G N VT 6 VT<B 7B # T<B 8B # 4ETF<B 9B # T<B :B # 4T<B ;B # 3T4<B <B # 4T<B =B # |T}<B >B # 4 T!<B ?B # T<B @B # 4iTj<B AB # T<B BB # 4T<B CB # VTW D 6  n C0.0$G  E 6$  C0.1$G  F 6`/ ^ C0.2$G  G 6 : I C0.3$G  H 6D  C0.4$G  I 6`O 9 C0.5$G  J 6Y # C0.6$G  K 6d   Gx (y=0)$G  L < o [J fE/eV$G P M 3 '"`SX  O H| "`X 8CI   P H, "`t  8TS   Q H "`E4 [2B1 :     R H "`d [2A2 :     T HT "` A  :MIN   h2 W s *"`-h2 X s *"` 6 h2 Y s *"`j` _ 0 (Z  1D slice of the PES through the conical intersection (to the right) will be used throughout this presentation to show the value of energy fixed for each iso-energy surface. H  0޽h ? 3f___PPT10i.c*+D=' = @B +n(  0 '}' Uj'(  l  6A?"`"Zy `  s *"`_ p / L [  # | qh    B CDEFjJ2 c0@O_oF~o 0Su -<L,\Fl_|x %3*A:MIXYbilyt{'7GWg}wvne[QE9+%4DScst]F,!b1BA QaqjCC.k>N^n~,Qu9 Vs,<L\kz "7K]o )8HXhx  & 6 |F gV Qe 8u      p G    # I3 C S c Gs ` [\@"`N: N W ~   W ~ <B  # W  <B  # W w <B  # W w <B  # WW Xw <B  # W w <B  # W w <B  #  W  w <B   # U W V w <B ! #  W w <B " #  W w <B # #  W  <B $ # Q W R w <B % #  W w <B & #  W w <B ' #  W  w <B ( # O W P w <B ) #  W w <B * #  W w <B + #  W w <B , # L W M w <B - #  W <B . #  W w <B / #  W w <B 0 # I W J w <B 1 #  W w <B 2 #  W w <B 3 # W w <B 4 # FW Gw <B 5 # W w <B 6 # W w <B 7 # W  <B 8 # CW Dw <B 9 # W w <B : # W w <B ; # W w <B < # AW Bw <B = # W w <B > # W w <B ? # W w <B @ # =W >w <B A # }W ~  B 6P )  D-0.2$G  C 6[   D-0.1$G  D 6f   C0.0$G  E 60p j  C0.1$G  F 6z    C0.2$G N VT G VT<B HB # T<B IB # 4ETF<B JB # T<B KB # 4T<B LB # 3T4<B MB # 4T<B NB # |T}<B OB # 4 T!<B PB # T<B QB # 4iTj<B RB # T<B SB # 4T<B TB # VTW U 6n C0.0$G  V 6X C0.1$G  W 6؞^ C0.2$G  X 6I C0.3$G  Y 6 C0.4$G  Z 6ؾ9 C0.5$G  [ 6Xɺ# C0.6$G  \ 6Ժ  Gx (y=0)$G  ] <޺[J fE/eV$G P ^ 3 '"`SX  _ B|"`u 8CI   ` B"`6 8TS   a B"`A9  :MIN   `2 b s *"`6-M`2 c s *"``2 d s *"``jw h B%"` a  _ E = 0.02 eV 3 RB i s *D3Vl@m j 0<0  73D PES of Cyclic-N3 in the Hyperspherical Coordinates:80  # H  0޽h ? 33___PPT10i.a`'Z+D=' = @B +*  0 ))X`$((  $l $ 6A?"`"Zy l $ 6A?"`"Zy ` $ s *"`_ p / L [   $# | qh   $  B CDEFjJ2 c0@O_oF~o 0Su -<L,\Fl_|x %3*A:MIXYbilyt{'7GWg}wvne[QE9+%4DScst]F,!b1BA QaqjCC.k>N^n~,Qu9 Vs,<L\kz "7K]o )8HXhx  & 6 |F gV Qe 8u      p G    # I3 C S c Gs ` [\@"`N: N W ~   $ W ~ <B  $ # W  <B  $ # W w <B $ # W w <B $ # WW Xw <B $ # W w <B $ # W w <B $ #  W  w <B $ # U W V w <B $ #  W w <B $ #  W w <B $ #  W  <B $ # Q W R w <B $ #  W w <B $ #  W w <B $ #  W  w <B $ # O W P w <B $ #  W w <B $ #  W w <B $ #  W w <B $ # L W M w <B  $ #  W <B !$ #  W w <B "$ #  W w <B #$ # I W J w <B $$ #  W w <B %$ #  W w <B &$ # W w <B '$ # FW Gw <B ($ # W w <B )$ # W w <B *$ # W  <B +$ # CW Dw <B ,$ # W w <B -$ # W w <B .$ # W w <B /$ # AW Bw <B 0$ # W w <B 1$ # W w <B 2$ # W w <B 3$ # =W >w <B 4$ # }W ~  5$ 6F )  D-0.2$G  6$ 6TW   D-0.1$G  7$ 6Xa   C0.0$G  8$ 6j j  C0.1$G  9$ 6t    C0.2$G N VT :$ VT<B ;$B # T<B <$B # 4ETF<B =$B # T<B >$B # 4T<B ?$B # 3T4<B @$B # 4T<B A$B # |T}<B B$B # 4 T!<B C$B # T<B D$B # 4iTj<B E$B # T<B F$B # 4T<B G$B # VTW H$ 64n C0.0$G  I$ 6 C0.1$G  J$ 6^ C0.2$G  K$ 68I C0.3$G  L$ 6 C0.4$G  M$ 69 C0.5$G  N$ 6伩# C0.6$G  O$ 6Ʃ  Gx (y=0)$G  P$ <Щ[J fE/eV$G P Q$ 3 '"`SX  R$ B|۩"`u 8CI   S$ B"`6 8TS   T$ B"`A9  :MIN   `2 U$ s *"`6-M`2 V$ s *"``2 W$ s *"``jw Z$ Bp"` [c  a E = 0.0386 eV3 RB ]$ s *D3VA!BXB ^$ 0D3VA2B _$ 0$  73D PES of Cyclic-N3 in the Hyperspherical Coordinates:80  #  `$ <$   MReaches transition state...H $ 0޽h ? 3f___PPT10i.e@+D=' = @B +)  0 )(X`(((  (l ( 6A?"`"Zy ` ( s *"`_ p / L [  (# | qh  (  B CDEFjJ2 c0@O_oF~o 0Su -<L,\Fl_|x %3*A:MIXYbilyt{'7GWg}wvne[QE9+%4DScst]F,!b1BA QaqjCC.k>N^n~,Qu9 Vs,<L\kz "7K]o )8HXhx  & 6 |F gV Qe 8u      p G    # I3 C S c Gs ` [\@"`N: N W ~  ( W ~ <B  ( # W  <B  ( # W w <B  ( # W w <B  ( # WW Xw <B  ( # W w <B ( # W w <B ( #  W  w <B ( # U W V w <B ( #  W w <B ( #  W w <B ( #  W  <B ( # Q W R w <B ( #  W w <B ( #  W w <B ( #  W  w <B ( # O W P w <B ( #  W w <B ( #  W w <B ( #  W w <B ( # L W M w <B ( #  W <B ( #  W w <B ( #  W w <B  ( # I W J w <B !( #  W w <B "( #  W w <B #( # W w <B $( # FW Gw <B %( # W w <B &( # W w <B '( # W  <B (( # CW Dw <B )( # W w <B *( # W w <B +( # W w <B ,( # AW Bw <B -( # W w <B .( # W w <B /( # W w <B 0( # =W >w <B 1( # }W ~  2( 6$  )  D-0.2$G  3( 6   D-0.1$G  4( 6   C0.0$G  5( 6T j  C0.1$G  6( 6@C    C0.2$G N VT 7( VT<B 8(B # T<B 9(B # 4ETF<B :(B # T<B ;(B # 4T<B <(B # 3T4<B =(B # 4T<B >(B # |T}<B ?(B # 4 T!<B @(B # T<B A(B # 4iTj<B B(B # T<B C(B # 4T<B D(B # VTW E( 6n C0.0$G  F( 6  C0.1$G  G( 6쓹^ C0.2$G  H( 6I C0.3$G  I( 6P C0.4$G  J( 69 C0.5$G  K( 6캹# C0.6$G  L( 6Ĺ  Gx (y=0)$G  M( <hι[J fE/eV$G P N( 3 '"`SX  O( B8ٹ"`u 8CI   P( B"`6 8TS   Q( Bx"`A9  :MIN   `2 R( s *"`6-M`2 S( s *"``2 T( s *"``jw Z( BQ"` [  ` E = 0.162 eV 3 RB \( s *D3V-5-RB ]( s *D3V-.XB ^( 0D3V-:. _( 0,$  73D PES of Cyclic-N3 in the Hyperspherical Coordinates:80  #  `( <$  m  NQuantum ZPE: ground state...H ( 0޽h ? 3f___PPT10i.ep 8+D=' = @B ++  0 **[f *(   f  0"`_ p / L [   # | qh     B CDEFjJ2 c0@O_oF~o 0Su -<L,\Fl_|x %3*A:MIXYbilyt{'7GWg}wvne[QE9+%4DScst]F,!b1BA QaqjCC.k>N^n~,Qu9 Vs,<L\kz "7K]o )8HXhx  & 6 |F gV Qe 8u      p G    # I3 C S c Gs ` [\@"`N: N W ~    W ~ <B   # W  <B   # W w <B   # W w <B   # WW Xw <B   # W w <B   # W w <B   #  W  w <B   # U W V w <B   #  W w <B   #  W w <B   #  W  <B   # Q W R w <B   #  W w <B   #  W w <B   #  W  w <B   # O W P w <B   #  W w <B   #  W w <B   #  W w <B   # L W M w <B   #  W <B   #  W w <B   #  W w <B   # I W J w <B !  #  W w <B "  #  W w <B #  # W w <B $  # FW Gw <B %  # W w <B &  # W w <B '  # W  <B (  # CW Dw <B )  # W w <B *  # W w <B +  # W w <B ,  # AW Bw <B -  # W w <B .  # W w <B /  # W w <B 0  # =W >w <B 1  # }W ~  2  6,$  )  D-0.2$G  3  6    D-0.1$G  4  6|    C0.0$G  5  6`  j  C0.1$G  6  6     C0.2$G N VT 7  VT<B 8 B # T<B 9 B # 4ETF<B : B # T<B ; B # 4T<B < B # 3T4<B = B # 4T<B > B # |T}<B ? B # 4 T!<B @ B # T<B A B # 4iTj<B B B # T<B C B # 4T<B D B # VTW E  6Pn C0.0$G  F  6x[ C0.1$G  G  6pe^ C0.2$G  H  6LoI C0.3$G  I  6y C0.4$G  J  69 C0.5$G  K  6# C0.6$G  L  6  Gx (y=0)$G  M  <[J fE/eV$G P N  3 '"`SX  O H"`u 8CI   P Hx"`6 8TS   S H8"`A9  :MIN   f2 T 0"`6-Mf2 U 0"`f2 V 0"``jwl [ 6A?"`"Zy l \ 6A?"`"Zy l ] 6A?"`"Zy l ^ 6A ?"`"Zy  _ BpE"` [  ` E = 0.520 eV 3 RB b s *D3V ;RB c s *D3VXB d 0D3VD e 0\@$  73D PES of Cyclic-N3 in the Hyperspherical Coordinates:80  #  f <$   T"Approaches conical intersection...##H  0޽h ? 3f___PPT10i.c/+D=' = @B +L   0   \4 (  \ \ <( PNp n0Explanation of the Hyper-spherical Coordinates: "10l \ 6A?"`)$ x  L EJ3  \# # `B \ 0DExB \ HD ^J3 `B  \ 0DEJ\xB  \ HD 3 lB  \ <D  ^2  \ S B|C'wE$GHI`TQ 'w|? 'w|? `T`T'w|? `T`T"`g xB  \ HDP- _ZB \B s *D}  ZB \ s *D  \ B $"`u 3x \ B$"` g  3y \ B,$"` OG # 5r \ B|b$"`mUA 5f \ Hw2L"` Ttan(q/2)0 ZB \ s *D  'ZB \ s *D  H \ 0޽h ? \ 3F43380___PPT10.j  r0@4P&x @ 5 1( / 0DArialew RomanTT+ܖ 0ܖ"DTahomaew RomanTT+ܖ 0ܖ" DWingdingsRomanSlide 5Slide 6Slide 7  Fonts UsedDesign Template Slide Titles_ BruceBrucekovd4 $,    _ !"$%&'()*+,-./0123456789:;<=>?@ABCDEFGHIJKLMNOPQRSTUVWXYZ[\]^_`abcdefghijklmnoprstuvwxyz{|}~ 6Slide 7  Fonts UsedDesign Template Slide Titles _babikovdbabikovd HD #^ dB  \ <DF F +2  \ S B|C'wE$GHI`TQ 'w|? 'w|? `T`T'w|? `T`T"`4 pB  \ HDE ,RB \@ s *DO - RB \ s *D e  \ B $"`n GB  7x \ B$"`` <4  7y \ B,$"`5+  9r \ B|b$"`: 1  9f \ Hw2L"`{O  `tan(q/2)< RB \ s *D  RB \ s *D D H \ 0޽h ? \ 3F433___PPT10i.j  +D=' = @B +r !. 1( / 0DArialew RomanTT+ܖ 0ܖ"DTahomaew RomanTT+ܖ 0ܖ" DWingdingsRomanTT+ܖ 0ܖ0DCourier NewmanTT+ܖ 0ܖ1@DTimes New RomanTT+ܖ 0ܖPDSymbolew RomanTT+ܖ 0ܖ@ .  @n?" dd@  @@`` \k` g aa..$$b$J(Mhu$b$DIN; lM$$b$@!>чR1jb${7c7I9K 0AA`3@8    3ʚ;ʚ;g4bdbdS 0@ppp@ <4dddd w 0T+ 80___PPT10 ?  %  r/.7 1( / 0DArialew RomanTT+ܖ 0ܖ"DTahomaew RomanTT+ܖ 0ܖ" DWingdingsRomanTT+ܖ 0ܖ0DCourier NewmanTT+ܖ 0ܖ1@DTimes New RomanTT+ܖ 0ܖPDSymbolew RomanTT+ܖ 0ܖ@ .  @n?" dd@  @@`` \k` g aa..$$b$J(Mhu$b$DIN; lM$$b$@!>чR1jb${7c7I9K 0AA`3@8    3ʚ;ʚ;g4bdbdS 0@ppp@ <4dddd w 0T+ 80___PPT10 ?  %     0   \U (  \ \ # B C DEFAr T x @"`nD \ <(  X {& o1Explanation of the Hyper-spherical Coordinates: "21l \ 6A?"`W XB \ 0D$ pB \ HD+_  XB  \ 0D)pB  \ HD #^ dB  \ <DF F +2  \ S B|C'wE$GHI`TQ 'w|? 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I0퇈 _#??kr๤B6;1 "K` )>007?#$!9΄-^jZXDLrdba៾(H`݁eGGEG'xY _>`̵[]LWGG{HHHW | "4@uĈĘ X<!F}߳9 irL` ||"cqlK-Q `u !14x< kS ul5< _S#qA0@@`kceibi΄mg6:;cf7@)j 9oϾ KNsF{y 6..1@@@ 5]Un0pBiu<ҽ '᳭u01F#v`8's07|2:(F`#bQ0F1(F`#bQ0(F`#bQ0F1(F`#bQ0F1(F`#bQ0F1(F`#bQ0F1tnvϚIENDB`0ܖ 0ܖPDSymbolew RomanTT0ܖ 0ܖ@ .  @n?" dd@  @@`` 2`  k` g aa..2b$k9=ƢIb$sճEHpM~$/Cb!b$J(Mhub$?7PϱP"jôb$DIN; lMb$C6dضl4$b$@!>чR1jb${7c7I9K 0AA`3@8    3ʚ;ʚ;g4bdbdH_ 0 ppp@ <4dddd w 0T/ 80___PPT10 ?  %      0 um1`(  `f /` 0"`  f 0` 0"`K ^f 1` 0"` f .` 0"`Dz Wr ` <'A?"` r ` <'A?"`o {r ` <'A?"`O  [r ` <'A?"`? t K ` B<   ;(0,0,0) ` B< F | ;(0,0,2) ` B0<  #  ;(0,1,0) ` B%<  k   ;(0,1,2)M ,` 0hR Y qExamples of vibrational wavefunctions for Cyclic-N3 Assignment: (symmetric stretch, bend, anti-symmetric stretch),r2 >,  MH ` 0޽h ? 3F43380___PPT10.ʃsrGL fT#Ls] 1( / 0DArialew RomanTT0ܖ 0ܖ"DTahomaew RomanTT0ܖ 0ܖ" DWingdingsRomanTT0ܖ 0ܖ0DCourier NewmanTT0ܖ 0ܖ1@DTimes New RomanTT0ܖ 0ܖPDSymbolew RomanTT0ܖ 0ܖ@ .  @n?" dd@  @@`` 2`  k` g aa..2b$k9=ƢIb$sճEHpM~$/Cb!b$J(Mhub$?7PϱP"jôb$DIN; lMb$C6dضl4$b$@!>чR1jb${7c7I9K 0AA`3@8    3ʚ;ʚ;g4bdbdH_ 0ppp@ <4dddd w 0T/ 80___PPT10 ?  %   n(  0 '}' Uj'(  l  6A?"`"Zy `  s *"`_ p / L [  # | qh    B CDEFjJ2 c0@O_oF~o 0Su -<L,\Fl_|x %3*A:MIXYbilyt{'7GWg}wvne[QE9+%4DScst]F,!b1BA QaqjCC.k>N^n~,Qu9 Vs,<L\kz "7K]o )8HXhx  & 6 |F gV Qe 8u      p G    # I3 C S c Gs ` [\@"`N: N W ~   W ~ <B  # W  <B  # W w <B  # W w <B  # WW Xw <B  # W w <B  # W w <B  #  W  w <B   # U W V w <B ! #  W w <B " #  W w <B # #  W  <B $ # Q W R w <B % #  W w <B & #  W w <B ' #  W  w <B ( # O W P w <B ) #  W w <B * #  W w <B + #  W w <B , # L W M w <B - #  W <B . #  W w <B / #  W w <B 0 # I W J w <B 1 #  W w <B 2 #  W w <B 3 # W w <B 4 # FW Gw <B 5 # W w <B 6 # W w <B 7 # W  <B 8 # CW Dw <B 9 # W w <B : # W w <B ; # W w <B < # AW Bw <B = # W w <B > # W w <B ? # W w <B @ # =W >w <B A # }W ~  B 65 )  D-0.2$G  C 6:   D-0.1$G  D 6@   C0.0$G  E 6pE j  C0.1$G  F 6I    C0.2$G N VT G VT<B HB # T<B IB # 4ETF<B JB # T<B KB # 4T<B LB # 3T4<B MB # 4T<B NB # |T}<B OB # 4 T!<B PB # T<B QB # 4iTj<B RB # T<B SB # 4T<B TB # VTW U 6Rn C0.0$G  V 6X C0.1$G  W 6x\^ C0.2$G  X 6I C0.3$G  Y 6 C0.4$G  Z 6С9 C0.5$G  [ 6D# C0.6$G  \ 6  Gx (y=0)$G  ] <,[J fE/eV$G P ^ 3 '"`SX  _ Bdd"`u 8CI   ` B"`6 8TS   a Bp"`A9  :MIN   `2 b s *"`6-M`2 c s *"``2 d s *"``jw h Bt"`% _ E=0.02 eV 3RB i s *D3Vl@m j 0z  73D PES of Cyclic-N3 in the Hyperspherical Coordinates:80  # H  0޽h ? 33___PPT10i.a`'Z+D=' h= @B +*  0 ))X`$((  $l $ 6A?"`"Zy l $ 6A?"`"Zy ` $ s *"`_ p / L [   $# | qh   $  B CDEFjJ2 c0@O_oF~o 0Su -<L,\Fl_|x %3*A:MIXYbilyt{'7GWg}wvne[QE9+%4DScst]F,!b1BA QaqjCC.k>N^n~,Qu9 Vs,<L\kz "7K]o )8HXhx  & 6 |F gV Qe 8u      p G    # I3 C S c Gs ` [\@"`N: N W ~   $ W ~ <B  $ # W  <B  $ # W w <B $ # W w <B $ # WW Xw <B $ # W w <B $ # W w <B $ #  W  w <B $ # U W V w <B $ #  W w <B $ #  W w <B $ #  W  <B $ # Q W R w <B $ #  W w <B $ #  W w <B $ #  W  w <B $ # O W P w <B $ #  W w <B $ #  W w <B $ #  W w <B $ # L W M w <B  $ #  W <B !$ #  W w <B "$ #  W w <B #$ # I W J w <B $$ #  W w <B %$ #  W w <B &$ # W w <B '$ # FW Gw <B ($ # W w <B )$ # W w <B *$ # W  <B +$ # CW Dw <B ,$ # W w <B -$ # W w <B .$ # W w <B /$ # AW Bw <B 0$ # W w <B 1$ # W w <B 2$ # W w <B 3$ # =W >w <B 4$ # }W ~  5$ 6 )  D-0.2$G  6$ 6   D-0.1$G  7$ 6   C0.0$G  8$ 6p j  C0.1$G  9$ 6    C0.2$G N VT :$ VT<B ;$B # T<B <$B # 4ETF<B =$B # T<B >$B # 4T<B ?$B # 3T4<B @$B # 4T<B A$B # |T}<B B$B # 4 T!<B C$B # T<B D$B # 4iTj<B E$B # T<B F$B # 4T<B G$B # VTW H$ 6n C0.0$G  I$ 6 C0.1$G  J$ 6x^ C0.2$G  K$ 68I C0.3$G  L$ 6 C0.4$G  M$ 69 C0.5$G  N$ 6x# C0.6$G  O$ 68  Gx (y=0)$G  P$ <[J fE/eV$G P Q$ 3 '"`SX  R$ B "`u 8CI   S$ Bx"`6 8TS   T$ BP"`A9  :MIN   `2 U$ s *"`6-M`2 V$ s *"``2 W$ s *"``jw Z$ B"`[ ` E=0.034 eV 3RB ]$ s *D3VA!BXB ^$ 0D3VA2B _$ 0\  73D PES of Cyclic-N3 in the Hyperspherical Coordinates:80  #  `$ <   MReaches transition state...H $ 0޽h ? 3f___PPT10i.e@+D=' h= @B +)  0 )(X`(((  (l ( 6A?"`"Zy ` ( s *"`_ p / L [  (# | qh  (  B CDEFjJ2 c0@O_oF~o 0Su -<L,\Fl_|x %3*A:MIXYbilyt{'7GWg}wvne[QE9+%4DScst]F,!b1BA QaqjCC.k>N^n~,Qu9 Vs,<L\kz "7K]o )8HXhx  & 6 |F gV Qe 8u      p G    # I3 C S c Gs ` [\@"`N: N W ~  ( W ~ <B  ( # W  <B  ( # W w <B  ( # W w <B  ( # WW Xw <B  ( # W w <B ( # W w <B ( #  W  w <B ( # U W V w <B ( #  W w <B ( #  W w <B ( #  W  <B ( # Q W R w <B ( #  W w <B ( #  W w <B ( #  W  w <B ( # O W P w <B ( #  W w <B ( #  W w <B ( #  W w <B ( # L W M w <B ( #  W <B ( #  W w <B ( #  W w <B  ( # I W J w <B !( #  W w <B "( #  W w <B #( # W w <B $( # FW Gw <B %( # W w <B &( # W w <B '( # W  <B (( # CW Dw <B )( # W w <B *( # W w <B +( # W w <B ,( #       !"#$%&'()*+,-./0123456789:;<=>?@ABCDEFGHIJKLMNOPQRSTUVWXYZ[\]^_`abcdefghijklmnopqrstuvwxz{|}~AW Bw <B -( # W w <B .( # W w <B /( # W w <B 0( # =W >w <B 1( # }W ~  2( 6 )  D-0.2$G  3( 6   D-0.1$G  4( 6,    C0.0$G  5( 6( j  C0.1$G  6( 6    C0.2$G N VT 7( VT<B 8(B # T<B 9(B # 4ETF<B :(B # T<B ;(B # 4T<B <(B # 3T4<B =(B # 4T<B >(B # |T}<B ?(B # 4 T!<B @(B # T<B A(B # 4iTj<B B(B # T<B C(B # 4T<B D(B # VTW E( 6Tn C0.0$G  F( 6l" C0.1$G  G( 6&^ C0.2$G  H( 6+I C0.3$G  I( 6`0 C0.4$G  J( 6 59 C0.5$G  K( 69# C0.6$G  L( 6>  Gx (y=0)$G  M( <`C[J fE/eV$G P N( 3 '"`SX  O( BH"`u 8CI   P( BL"`6 8TS   Q( BP"`A9  :MIN   `2 R( s *"`6-M`2 S( s *"``2 T( s *"``jw Z( B V"`c 7 _ E=0.16 eV 3RB \( s *D3V-5-RB ]( s *D3V-.XB ^( 0D3V-:. _( 0Z  73D PES of Cyclic-N3 in the Hyperspherical Coordinates:80  #  `( <,a  m  NQuantum ZPE: ground state...H ( 0޽h ? 3f___PPT10i.ep 8+D=' h= @B ++  0 **[f *(   f  0"`_ p / L [   # | qh     B CDEFjJ2 c0@O_oF~o 0Su -<L,\Fl_|x %3*A:MIXYbilyt{'7GWg}wvne[QE9+%4DScst]F,!b1BA QaqjCC.k>N^n~,Qu9 Vs,<L\kz "7K]o )8HXhx  & 6 |F gV Qe 8u      p G    # I3 C S c Gs ` [\@"`N: N W ~    W ~ <B   # W  <B   # W w <B   # W w <B   # WW Xw <B   # W w <B   # W w <B   #  W  w <B   # U W V w <B   #  W w <B   #  W w <B   #  W  <B   # Q W R w <B   #  W w <B   #  W w <B   #  W  w <B   # O W P w <B   #  W w <B   #  W w <B   #  W w <B   # L W M w <B   #  W <B   #  W w <B   #  W w <B   # I W J w <B !  #  W w <B "  #  W w <B #  # W w <B $  # FW Gw <B %  # W w <B &  # W w <B '  # W  <B (  # CW Dw <B )  # W w <B *  # W w <B +  # W w <B ,  # AW Bw <B -  # W w <B .  # W w <B /  # W w <B 0  # =W >w <B 1  # }W ~  2  6Pt )  D-0.2$G  3  6\y   D-0.1$G  4  6x~   C0.0$G  5  6 j  C0.1$G  6  6T    C0.2$G N VT 7  VT<B 8 B # T<B 9 B # 4ETF<B : B # T<B ; B # 4T<B < B # 3T4<B = B # 4T<B > B # |T}<B ? B # 4 T!<B @ B # T<B A B # 4iTj<B B B # T<B C B # 4T<B D B # VTW E  6n C0.0$G  F  6( C0.1$G  G  6^ C0.2$G  H  6I C0.3$G  I  6 C0.4$G  J  6|9 C0.5$G  K  6d# C0.6$G  L  6  Gx (y=0)$G  M  <\[J fE/eV$G P N  3 '"`SX  O H$"`u 8CI   P HX"`6 8TS   S H"`A9  :MIN   f2 T 0"`6-Mf2 U 0"`f2 V 0"``jwl [ 6A?"`"Zy l \ 6A?"`"Zy l ] 6A?"`"Zy l ^ 6A ?"`"Zy  _ B"`Y - a E = 0.52 eV 3 RB b s *D3V ;RB c s *D3VXB d 0D3VD e 0@  73D PES of Cyclic-N3 in the Hyperspherical Coordinates:80  #  f <   T"Approaches conical intersection...##H  0޽h ? 3f___PPT10i.c/+D=' h= @B +r$]e BD P]  1( / 0DArialew RomanTT0ܖ 0ܖ"DTahomaew RomanTT0ܖ 0ܖ" DWingdingsRomanTT0ܖ 0ܖ0DCourier NewmanTT0ܖ 0ܖ1@DTimes New RomanTT0ܖ 0ܖPDSymbolew RomanTT0ܖ 0ܖ@ .  @n?" dd@  @@`` 2`  k` g aa..2b$k9=ƢIb$sճEHpM~$/Cb!b$J(Mhub$?7PϱP"jôb$DIN; lMb$C6dضl4$b$@!>чR1jb${7c7I9K 0AA`3@8    3ʚ;ʚ;g4bdbdH_ 0ppp@ <4dddd w 0T/ 80___PPT10 ?  %   n(  0 '}' Uj'(  l  6A?"`"Zy `  s *"`_ p / L [  # | qh    B CDEFjJ2 c0@O_oF~o 0Su -<L,\Fl_|x %3*A:MIXYbilyt{'7GWg}wvne[QE9+%4DScst]F,!b1BA QaqjCC.k>N^n~,Qu9 Vs,<L\kz "7K]o )8HXhx  & 6 |F gV Qe 8u      p G    # I3 C S c Gs ` [\@"`N: N W ~   W ~ <B  # W  <B  # W w <B  # W w <B  # WW Xw <B  # W w <B  # W w <B  #  W  w <B   # U W V w <B ! #  W w <B " #  W w <B # #  W  <B $ # Q W R w <B % #  W w <B & #  W w <B ' #  W  w <B ( # O W P w <B ) #  W w <B * #  W w <B + #  W w <B , # L W M w <B - #  W <B . #  W w <B / #  W w <B 0 # I W J w <B 1 #  W w <B 2 #  W w <B 3 # W w <B 4 # FW Gw <B 5 # W w <B 6 # W w <B 7 # W  <B 8 # CW Dw <B 9 # W w <B : # W w <B ; # W w <B < # AW Bw <B = # W w <B > # W w <B ? # W w <B @ # =W >w <B A # }W ~  B 65 )  D-0.2$G  C 6:   D-0.1$G  D 6@   C0.0$G  E 6pE j  C0.1$G  F 6I    C0.2$G N VT G VT<B HB # T<B IB # 4ETF<B JB # T<B KB # 4T<B LB # 3T4<B MB # 4T<B NB # |T}<B OB # 4 T!<B PB # T<B QB # 4iTj<B RB # T<B SB # 4T<B TB # VTW U 6Rn C0.0$G  V 6X C0.1$G  W 6x\^ C0.2$G  X 6I C0.3$G  Y 6 C0.4$G  Z 6С9 C0.5$G  [ 6D# C0.6$G  \ 6  Gx (y=0)$G  ] <,[J fE/eV$G P ^ 3 '"`SX  _ Bdd"`u 8CI   ` B"`6 8TS   a Bp"`A9  :MIN   `2 b s *"`6-M`2 c s *"``2 d s *"``jw h Bt"`t _ E=0.02 eV 3RB i s *D3Vl@m j 0z  73D PES of Cyclic-N3 in the Hyperspherical Coordinates:80  # H  0޽h ? 33___PPT10i.a`'Z+D=' h= @B +*  0 ))X`$((  $l $ 6A?"`"Zy l $ 6A?"`"Zy ` $ s *"`_ p / L [   $# | qh   $  B CDEFjJ2 c0@O_oF~o 0Su -<L,\Fl_|x %3*A:MIXYbilyt{'7GWg}wvne[QE9+%4DScst]F,!b1BA QaqjCC.k>N^n~,Qu9 Vs,<L\kz "7K]o )8HXhx  & 6 |F gV Qe 8u      p G    # I3 C S c Gs ` [\@"`N: N W ~   $ W ~ <B  $ # W  <B  $ # W w <B $ # W w <B $ # WW Xw <B $ # W w <B $ # W w <B $ #  W  w <B $ # U W V w <B $ #  W w <B $ #  W w <B $ #  W  <B $ # Q W R w <B $ #  W w <B $ #  W w <B $ #  W  w <B $ # O W P w <B $ #  W w <B $ #  W w <B $ #  W w <B $ # L W M w <B  $ #  W <B !$ #  W w <B "$ #  W w <B #$ # I W J w <B $$ #  W w <B %$ #  W w <B &$ # W w <B '$ # FW Gw <B ($ # W w <B )$ # W w <B *$ # W  <B +$ # CW Dw <B ,$ # W w <B -$ # W w <B .$ # W w <B /$ # AW Bw <B 0$ # W w <B 1$ # W w <B 2$ # W w <B 3$ # =W >w <B 4$ # }W ~  5$ 6 )  D-0.2$G  6$ 6   D-0.1$G  7$ 6   C0.0$G  8$ 6p j  C0.1$G  9$ 6    C0.2$G N VT :$ VT<B ;$B # T<B <$B # 4ETF<B =$B # T<B >$B # 4T<B ?$B # 3T4<B @$B # 4T<B A$B # |T}<B B$B # 4 T!<B C$B # T<B D$B # 4iTj<B E$B # T<B F$B # 4T<B G$B # VTW H$ 6n C0.0$G  I$ 6 C0.1$G  J$ 6x^ C0.2$G  K$ 68I C0.3$G  L$ 6 C0.4$G  M$ 69 C0.5$G  N$ 6x# C0.6$G  O$ 68  Gx (y=0)$G  P$ <[J fE/eV$G P Q$ 3 '"`SX  R$ B "`u 8CI   S$ Bx"`6 8TS   T$ BP"`A9  :MIN   `2 U$ s *"`6-M`2 V$ s *"``2 W$ s *"``jw Z$ B"`R ` E=0.034 eV 3RB ]$ s *D3VA!BXB ^$ 0D3VA2B _$ 0\  73D PES of Cyclic-N3 in the Hyperspherical Coordinates:80  #  `$ <   MReaches transition state...H $ 0޽h ? 3f___PPT10i.e@+D=' h= @B +)  0 )(X`(((  (l ( 6A?"`"Zy ` ( s *"`_ p / L [  (# | qh  (  B CDEFjJ2 c0@O_oF~o 0Su -<L,\Fl_|x %3*A:MIXYbilyt{'7GWg}wvne[QE9+%4DScst]F,!b1BA QaqjCC.k>N^n~,Qu9 Vs,<L\kz "7K]o )8HXhx  & 6 |F gV Qe 8u      p G    # I3 C S c Gs ` [\@"`N: N W ~  ( W ~ <B  ( # W  <B  ( # W w <B  ( # W w <B  ( # WW Xw <B  ( # W w <B ( # W w <B ( #  W  w <B ( # U W V w <B ( #  W w <B ( #  W w <B ( #  W  <B ( # Q W R w <B ( #  W w <B ( #  W w <B ( #  W  w <B ( # O W P w <B ( #  W w <B ( #  W w <B ( #  W w <B ( # L W M w <B ( #  W <B ( #  W w <B ( #  W w <B  ( # I W J w <B !( #  W w <B "( #  W w <B #( # W w <B $( # FW Gw <B %( # W w <B &( # W w <B '( # W  <B (( # CW Dw <B )( # W w <B *( # W w <B +( # W w <B ,( # AW Bw <B -( # W w <B .( # W w <B /( # W w <B 0( # =W >w <B 1( # }W ~  2( 6 )  D-0.2$G  3( 6   D-0.1$G  4( 6,    C0.0$G  5( 6( j  C0.1$G  6( 6    C0.2$G N VT 7( VT<B 8(B # T<B 9(B # 4ETF<B :(B # T<B ;(B # 4T<B <(B # 3T4<B =(B # 4T<B >(B # |T}<B ?(B # 4 T!<B @(B # T<B A(B # 4iTj<B B(B # T<B C(B # 4T<B D(B # VTW E( 6Tn C0.0$G  F( 6l" C0.1$G  G( 6&^ C0.2$G  H( 6+I C0.3$G  I( 6`0 C0.4$G  J( 6 59 C0.5$G  K( 69# C0.6$G  L( 6>  Gx (y=0)$G  M( <`C[J fE/eV$G P N( 3 '"`SX  O( BH"`u 8CI   P( BL"`6 8TS   Q( BP"`A9  :MIN   `2 R( s *"`6-M`2 S( s *"``2 T( s *"``jw Z( B V"` q@ _ E=0.16 eV 3RB \( s *D3V-5-RB ]( s *D3V-.XB ^( 0D3V-:. _( 0Z  73D PES of Cyclic-N3 in the Hyperspherical Coordinates:80  #  `( <,a  m  NQuantum ZPE: ground state...H ( 0޽h ? 3f___PPT10i.ep 8+D=' h= @B ++  0 **[f *(   f  0"`_ p / L [   # | qh     B CDEFjJ2 c0@O_oF~o 0Su -<L,\Fl_|x %3*A:MIXYbilyt{'7GWg}wvne[QE9+%4DScst]F,!b1BA QaqjCC.k>N^n~,Qu9 Vs,<L\kz "7K]o )8HXhx  & 6 |F gV Qe 8u      p G    # I3 C S c Gs ` [\@"`N: N W ~    W ~ <B   # W  <B   # W w <B   # W w <B   # WW Xw <B   # W w <B   # W w <B   #  W  w <B   # U W V w <B   #  W w <B   #  W w <B   #  W  <B   # Q W R w <B   #  W w <B   #  W w <B   #  W  w <B   # O W P w <B   #  W w <B   #  W w <B   #  W w <B   # L W M w <B   #  W <B   #  W w <B   #  W w <B   # I W J w <B !  #  W w <B "  #  W w <B #  # W w <B $  # FW Gw <B %  # W w <B &  # W w <B '  # W  <B (  # CW Dw <B )  # W w <B *  # W w <B +  # W w <B ,  # AW Bw <B -  # W w <B .  # W w <B /  # W w <B 0  # =W >w <B 1  # }W ~  2  6Pt )  D-0.2$G  3  6\y   D-0.1$G  4  6x~   C0.0$G  5  6 j  C0.1$G  6  6T    C0.2$G N VT 7  VT<B 8 B # T<B 9 B # 4ETF<B : B # T<B ; B # 4T<B < B # 3T4<B = B # 4T<B > B # |T}<B ? B # 4 T!<B @ B # T<B A B # 4iTj<B B B # T<B C B # 4T<B D B # VTW E  6n C0.0$G  F  6( C0.1$G  G  6^ C0.2$G  H  6I C0.3$G  I  6 C0.4$G  J  6|9 C0.5$G  K  6d# C0.6$G  L  6  Gx (y=0)$G  M  <\[J fE/eV$G P N  3 '"`SX  O H$"`u 8CI   P HX"`6 8TS   S H"`A9  :MIN   f2 T 0"`6-Mf2 U 0"`f2 V 0"``jwl [ 6A?"`"Zy l \ 6A?"`"Zy l ] 6A?"`"Zy l ^ 6A ?"`"Zy  _ B"`j o* a E = 0.52 eV 3 RB b s *D3V ;RB c s *D3VXB d 0D3VD e 0@  73D PES of Cyclic-N3 in the Hyperspherical Coordinates:80  #  f <   T"Approaches conical intersection...##H  0޽h ? 3f___PPT10i.c/+D=' h= @B +r$= > h = 1( / 0DArialew RomanTT0ܖ 0ܖ"DTahomaew RomanTT0ܖ 0ܖ" DWingdingsRomanTT0ܖ 0ܖ0DCourier NewmanTT0ܖ 0ܖ1@DTimes New RomanTT0ܖ 0ܖPDSymbolew RomanTT0ܖ 0ܖ@ .  @n?" dd@  @@`` 2`  k` g aa..2b$k9=ƢIb$sճEHpM~$/Cb!b$J(Mhub$?7PϱP"jôb$DIN; lMb$C6dضl4$b$@!>чR1jb${7c7I9K 0AA`3@8    3ʚ;ʚ;g4bdbdH_ 0 ppp@ <4dddd w 0T/ 80___PPT10 ?  %   ri 1( / 0DArialew RomanTTܖ 0ܖDTahomaew RomanTTܖ 0ܖ" DWingdingsRomanTTܖ 0ܖ0DCourier NewmanTTܖ 0ܖ1@DTimes New RomanTTܖ 0ܖPDSymbolew RomanTTܖ 0ܖ@ .  @n?" dd@  @@`` 2`  k` g aa..2b$k9=ƢIb$sճEHpM~$/Cb!b$J(Mhub$?7PϱP"jôb$DIN; lMb$C6dضl4$b$@!>чR1jb${7c7I9K 0AA`3@8    3ʚ;ʚ;g4sdsd  0ppp@ <4dddd w 0T 80___PPT10 ?  %   &*  0 =)5)X`(((  (l ( 6A?"`"Zy ` ( s *"`_ p / L [  (# | qh  (  B CDEFjJ2 c0@O_oF~o 0Su -<L,\Fl_|x %3*A:MIXYbilyt{'7GWg}wvne[QE9+%4DScst]F,!b1BA QaqjCC.k>N^n~,Qu9 Vs,<L\kz "7K]o )8HXhx  & 6 |F gV Qe 8u      p G    # I3 C S c Gs ` [\@"`N: N W ~  ( W ~ <B  ( # W  <B  ( # W w <B  ( # W w <B  ( # WW Xw <B  ( # W w <B ( # W w <B ( #  W  w <B ( # U W V w <B ( #  W w <B ( #  W w <B ( #  W  <B ( # Q W R w <B ( #  W w <B ( #  W w <B ( #  W  w <B ( # O W P w <B ( #  W w <B ( #  W w <B ( #  W w <B ( # L W M w <B ( #  W <B ( #  W w <B ( #  W w <B  ( # I W J w <B !( #  W w <B "( #  W w <B #( # W w <B $( # FW Gw <B %( # W w <B &( # W w <B '( # W  <B (( # CW Dw <B )( # W w <B *( # W w <B +( # W w <B ,( # AW Bw <B -( # W w <B .( # W w <B /( # W w <B 0( # =W >w <B 1( # }W ~  2( 6,F )  D-0.2$G  3( 6(F   D-0.1$G  4( 6F   C0.0$G  5( 64F j  C0.1$G  6( 6A    C0.2$G N VT 7( VT<B 8(B # T<B 9(B # 4ETF<B :(B # T<B ;(B # 4T<B <(B # 3T4<B =(B # 4T<B >(B # |T}<B ?(B # 4 T!<B @(B # T<B A(B # 4iTj<B B(B # T<B C(B # 4T<B D(B # VTW E( 6An C0.0$G  F( 6A C0.1$G  G( 6A^ C0.2$G  H( 6#AI C0.3$G  I( 6\'A C0.4$G  J( 6,A9 C0.5$G  K( 6 A# C0.6$G  L( 61A  Gx (y=0)$G  M( <5A[J fE/eV$G P N( 3 '"`SX  O( BA"`u 8CI   P( B8чR1jb${7c7I9K 0AA`3@8    3ʚ;ʚ;g4sdsd  0ppp@ <4dddd w 0T 80___PPT10 ?  %   riE 1( / 0DArialew RomanTTܖ 0ܖDTahomaew RomanTTܖ 0ܖ" DWingdingsRomanTTܖ 0ܖ0DCourier NewmanTTܖ 0ܖ1@DTimes New RomanTTܖ 0ܖPDSymbolew RomanTTܖ 0ܖ@ .  @n?" dd@  @@`` 2`  la g aa..2b$k9=ƢIb$sճEHpM~$/Cb!b$J(Mhub$?7PϱP"jôb$DIN; lMb$C6dضl4$b$@!>чR1jb${7c7I9K 0AA`3@8    3ʚ;ʚ;g4dd  0vppp@ <4dddd w 0T 80___PPT10 ?  %   <)  0 S(K( Vk'(  l  6A?"`"Zy `  s *"`_ p / L [  # | qh    B CDEFjJ2 c0@O_oF~o 0Su -<L,\Fl_|x %3*A:MIXYbilyt{'7GWg}wvne[QE9+%4DScst]F,!b1BA QaqjCC.k>N^n~,Qu9 Vs,<L\kz "7K]o )8HXhx  & 6 |F gV Qe 8u      p G    # I3 C S c Gs ` [\@"`N: N W ~   W ~ <B  # W  <B  # W w <B  # W w <B  # WW Xw <B  # W w <B  # W w <B  #  W  w <B   # U W V w <B ! #  W w <B " #  W w <B # #  W  <B $ # Q W R w <B % #  W w <B & #  W w <B ' #  W  w <B ( # O W P w <B ) #  W w <B * #  W w <B + #  W w <B , # L W M w <B - #  W <B . #  W w <B / #  W w <B 0 # I W J w <B 1 #  W w <B 2 #  W w <B 3 # W w <B 4 # FW Gw <B 5 # W w <B 6 # W w <B 7 # W  <B 8 # CW Dw <B 9 # W w <B : # W w <B ; # W w <B < # AW Bw <B = # W w <B > # W w <B ? # W w <B @ # =W >w <B A # }W ~  B 6|6 )  D-0.2$G  C 6   D-0.1$G  D 6   C0.0$G  E 6l  j  C0.1$G  F 6    C0.2$G N VT G VT<B HB # T<B IB # 4ETF<B JB # T<B KB # 4T<B LB # 3T4<B MB # 4T<B NB # |T}<B OB # 4 T!<B PB # T<B QB # 4iTj<B RB # T<B SB # 4T<B TB # VTW U 6\8Fn C0.0$G  V 6,  f4Sits at the bottom of the wells... (there are three)55H  0޽h ? 33___PPT10i.a`'Z+D=' += @B +*  0 -)%)X`$((  $l $ 6A?"`"Zy l $ 6A?"`"Zy ` $ s *"`_ p / L [   $# | qh   $  B CDEFjJ2 c0@O_oF~o 0Su -<L,\Fl_|x %3*A:MIXYbilyt{'7GWg}wvne[QE9+%4DScst]F,!b1BA QaqjCC.k>N^n~,Qu9 Vs,<L\kz "7K]o )8HXhx  & 6 |F gV Qe 8u      p G    # I3 C S c Gs ` [\@"`N: N W ~   $ W ~ <B  $ # W  <B  $ # W w <B $ # W w <B $ # WW Xw <B $ # W w <B $ # W w <B $ #  W  w <B $ # U W V w <B $ #  W w <B $ #  W w <B $ #  W  <B $ # Q W R w <B $ #  W w <B $ #  W w <B $ #  W  w <B $ # O W P w <B $ #  W w <B $ #  W w <B $ #  W w <B $ # L W M w <B  $ #  W <B !$ #  W w <B "$ #  W w <B #$ # I W J w <B $$ #  W w <B %$ #  W w <B &$ # W w <B '$ # FW Gw <B ($ # W w <B )$ # W w <B *$ # W  <B +$ # CW Dw <B ,$ # W w <B -$ # W w <B .$ # W w <B /$ # AW Bw <B 0$ # W w <B 1$ # W w <B 2$ # W w <B 3$ # =W >w <B 4$ # }W ~  5$ 6F )  D-0.2$G  6$ 6F   D-0.1$G  7$ 6F   C0.0$G  8$ 6DF j  C0.1$G  9$ 6F    C0.2$G N VT :$ VT<B ;$B # T<B <$B # 4ETF<B =$B # T<B >$B # 4T<B ?$B # 3T4<B @$B # 4T<B A$B # |T}<B B$B # 4 T!<B C$B # T<B D$B # 4iTj<B E$B # T<B F$B # 4T<B G$B # VTW H$ 6dDFn C0.0$G  I$ 6EF C0.1$G  J$ 6IF^ C0.2$G  K$ 68FI C0.3$G  L$ 6+F C0.4$G  M$ 60F9 C0.5$G  N$ 64F# C0.6$G  O$ 6$F  Gx (y=0)$G  P$ <F[J fE/eV$G P Q$ 3 '"`SX  R$ BF"`u 8CI   S$ BF"`6 8TS   T$ BhF"`A9  :MIN   `2 U$ s *"`6-M`2 V$ s *"``2 W$ s *"``jw Z$ BF"`R ` E=0.034 eV 3RB ]$ s *D3VA!BXB ^$ 0D3VA2B _$ 0F  73D PES of Cyclic-N3 in the Hyperspherical Coordinates:80  #  `$ < F   _-Reaches transition state... (there are three)..H $ 0޽h ? 3f___PPT10i.e@+D=' += @B +6*  0 M)E)X`(((  (l ( 6A?"`"Zy ` ( s *"`_ p / L [  (# | qh  (  B CDEFjJ2 c0@O_oF~o 0Su -<L,\Fl_|x %3*A:MIXYbilyt{'7GWg}wvne[QE9+%4DScst]F,!b1BA QaqjCC.k>N^n~,Qu9 Vs,<L\kz "7K]o )8HXhx  & 6 |F gV Qe 8u      p G    # I3 C S c Gs ` [\@"`N: N W ~  ( W ~ <B  ( # W  <B  ( # W w <B  ( # W w <B  ( # WW Xw <B  ( # W w <B ( # W w <B ( #  W  w <B ( # U W V w <B ( #  W w <B ( #  W w <B ( #  W  <B ( # Q W R w <B ( #  W w <B ( #  W w <B ( #  W  w <B ( # O W P w <B ( #  W w <B ( #  W w <B ( #  W w <B ( # L W M w <B ( #  W <B ( #  W w <B ( #  W w <B  ( # I W J w <B !( #  W w <B "( #  W w <B #( # W w <B $( # FW Gw <B %( # W w <B &( # W w <B '( # W  <B (( # CW Dw <B )( # W w <B *( # W w <B +( # W w <B ,( # AW Bw <B -( # W w <B .( # W w <B /( # W w <B 0( # =W >w <B 1( # }W ~  2( 6,F )  D-0.2$G  3( 6(F   D-0.1$G  4( 6F   C0.0$G  5( 64F j  C0.1$G  6( 6A    C0.2$G N VT 7( VT<B 8(B # T<B 9(B # 4ETF<B :(B # T<B ;(B # 4T<B <(B # 3T4<B =(B # 4T<B >(B # |T}<B ?(B # 4 T!<B @(B # T<B A(B # 4iTj<B B(B # T<B C(B # 4T<B D(B # VTW E( 6An C0.0$G  F( 6A C0.1$G  G( 6A^ C0.2$G  H( 6#AI C0.3$G  I( 6\'A C0.4$G  J( 6,A9 C0.5$G  K( 6 A# C0.6$G  L( 61A  Gx (y=0)$G  M( <5A[J fE/eV$G P N( 3 '"`SX  O( BA"`u 8CI   P( B8чR1jb${7c7I9K 0AA`3@8    3ʚ;ʚ;g4dd  0Fppp@ <4dddd w 0T 80___PPT10 ?  %   9*  0 P)H)X`$((  $l $ 6A?"`"Zy l $ 6A?"`"Zy ` $ s *"`_ p / L [   $# | qh   $  B CDEFjJ2 c0@O_oF~o 0Su -<L,\Fl_|x %3*A:MIXYbilyt{'7GWg}wvne[QE9+%4DScst]F,!b1BA QaqjCC.k>N^n~,Qu9 Vs,<L\kz "7K]o )8HXhx  & 6 |F gV Qe 8u      p G    # I3 C S c Gs ` [\@"`N: N W ~   $ W ~ <B  $ # W  <B  $ # W w <B $ # W w <B $ # WW Xw <B $ # W w <B $ # W w <B $ #  W  w <B $ # U W V w <B $ #  W w <B $ #  W w <B $ #  W  <B $ # Q W R w <B $ #  W w <B $ #  W w <B $ #  W  w <B $ # O W P w <B $ #  W w <B $ #  W w <B $ #  W w <B $ # L W M w <B  $ #  W <B !$ #  W w <B "$ #  W w <B #$ # I W J w <B $$ #  W w <B %$ #  W w <B &$ # W w <B '$ # FW Gw <B ($ # W w <B )$ # W w <B *$ # W  <B +$ # CW Dw <B ,$ # W w <B -$ # W w <B .$ # W w <B /$ # AW Bw <B 0$ # W w <B 1$ # W w <B 2$ # W w <B 3$ # =W >w <B 4$ # }W ~  5$ 6F )  D-0.2$G  6$ 6F   D-0.1$G  7$ 6F   C0.0$G  8$ 6DF j  C0.1$G  9$ 6F    C0.2$G N VT :$ VT<B ;$B # T<B <$B # 4ETF<B =$B # T<B >$B # 4T<B ?$B # 3T4<B @$B # 4T<B A$B # |T}<B B$B # 4 T!<B C$B # T<B D$B # 4iTj<B E$B # T<B F$B # 4T<B G$B # VTW H$ 6dDFn C0.0$G  I$ 6EF C0.1$G  J$ 6IF^ C0.2$G  K$ 68FI C0.3$G  L$ 6+F C0.4$G  M$ 60F9 C0.5$G  N$ 64F# C0.6$G  O$ 6$F  Gx (y=0)$G  P$ <F[J fE/eV$G P Q$ 3 '"`SX  R$ BF"`u 8CI   S$ BF"`6 8TS   T$ BhF"`A9  :MIN   `2 U$ s *"`6-M`2 V$ s *"``2 W$ s *"``jw Z$ BF"`R ` E=0.034 eV 3RB ]$ s *D3VA!BXB ^$ 0D3VA2B _$ 0F  73D PES of Cyclic-N3 in the Hyperspherical Coordinates:80  #  `$ < F r   .Reaches transition states... (there are three)// H $ 0޽h ? 3f___PPT10i.e@+D=' += @B +rLJ' 1( / 0DArialew RomanTT ܖ 0ܖDTahomaew RomanTT ܖ 0ܖ" DWingdingsRomanTT ܖ 0ܖ0DCourier NewmanTT ܖ 0ܖ1@DTimes New RomanTT ܖ 0ܖPDSymbolew RomanTT ܖ 0ܖ@ .  @n?" dd@  @@`` 2`  la g aa..2b$k9=ƢIb$sճEHpM~$/Cb!b$J(Mhub$?7PϱP"jôb$DIN; lMb$C6dضl4$b$@!>чR1jb${7c7I9K 0AA`3@8    3ʚ;ʚ;g4dd<  0Fppp@ <4dddd w 0Tp  80___PPT10 ?  %   <)  0 S(K( Vk'(  l  6A?"`"Zy `  s *"`_ p / L [  # | qh    B CDEFjJ2 c0@O_oF~o 0Su -<L,\Fl_|x %3*A:MIXYbilyt{'7GWg}wvne[QE9+%4DScst]F,!b1BA QaqjCC.k>N^n~,Qu9 Vs,<L\kz "7K]o )8HXhx  & 6 |F gV Qe 8u      p G    # I3 C S c Gs ` [\@"`N: N W ~   W ~ <B  # W  <B  # W w <B  # W w <B  # WW Xw <B  #      W w <B  # W w <B  #  W  w <B   # U W V w <B ! #  W w <B " #  W w <B # #  W  <B $ # Q W R w <B % #  W w <B & #  W w <B ' #  W  w <B ( # O W P w <B ) #  W w <B * #  W w <B + #  W w <B , # L W M w <B - #  W <B . #  W w <B / #  W w <B 0 # I W J w <B 1 #  W w <B 2 #  W w <B 3 # W w <B 4 # FW Gw <B 5 # W w <B 6 # W w <B 7 # W  <B 8 # CW Dw <B 9 # W w <B : # W w <B ; # W w <B < # AW Bw <B = # W w <B > # W w <B ? # W w <B @ # =W >w <B A # }W ~  B 6<[h  )  D-0.2$G  C 6h    D-0.1$G  D 6`h    C0.0$G  E 6 h  j  C0.1$G  F 6h     C0.2$G N VT G VT<B HB # T<B IB # 4ETF<B JB # T<B KB # 4T<B LB # 3T4<B MB # 4T<B NB # |T}<B OB # 4 T!<B PB # T<B QB # 4iTj<B RB # T<B SB # 4T<B TB # VTW U 6h n C0.0$G  V 6\c  C0.1$G  W 6t]c ^ C0.2$G  X 60ec I C0.3$G  Y 6Hjc  C0.4$G  Z 6nc 9 C0.5$G  [ 6|sc # C0.6$G  \ 6  f4Sits at the bottom of the wells... (there are three)55H  0޽h ? 33___PPT10i.a`'Z+D='  = @B +rc? 1( / 0DArialew RomanTT ܖ 0ܖDTahomaew RomanTT ܖ 0ܖ" DWingdingsRomanTT ܖ 0ܖ0DCourier NewmanTT ܖ 0ܖ1@DTimes New RomanTT ܖ 0ܖPDSymbolew RomanTT ܖ 0ܖ@ .  @n?" dd@  @@`` 2`  la g aa..2b$k9=ƢIb$sճEHpM~$/Cb!b$J(Mhub$?7PϱP"jôb$DIN; lMb$C6dضl4$b$@!>чR1jb${7c7I9K 0AA`3@8    3ʚ;ʚ;g4dd<  0Fppp@ <4dddd w 0Tp  80___PPT10 ?  %   r! 1( / 0DArialew RomanTT ܖ 0ܖDTahomaew RomanTT ܖ 0ܖ" DWingdingsRomanTT ܖ 0ܖ0DCourier NewmanTT ܖ 0ܖ1@DTimes New RomanTT ܖ 0ܖPDSymbolew RomanTT ܖ 0ܖ@ .  @n?" dd@  @@`` 2`  la g aa..2b$k9=ƢIb$sճEHpM~$/Cb!b$J(Mhub$?7PϱP"jôb$DIN; lMb$C6dضl4$b$@!>чR1jb${7c7I9K 0AA`3@8    3ʚ;ʚ;g4dd<  0Fppp@ <4dddd w 0Tp  80___PPT10 ?  %   rU1t 1Root EntrydO)pT"PicturesCurrent User 8SummaryInformation(4T     !#      !"#$%&'()*+,-./0123456789:;<=>?@ABCDEFGHIJKLMNOPQRSTUVWXYZ[\]^_`abcdefghijklmnopqrstuvwxz{|}~      !"#$%&'()*+,-./0123456789:;<>?@ABCDEFGHIJKLMNOPQRSTUVWXYZ[\]^_`abcdefghijklmnopqrstuvwxyz{|}~   _ !"$%&'()*+,-./0123456789:;<=>?@ABCDEFGHIJKLMNOPQRSTUVWXYZ[\]^_`abcdefghijklmnoprstuvwxyz{|}~      !"#$%&'()*+,-./0123x56789:;<=>?@ABCDEFGHIJKLMNOPQRSTUVWXYZ[\]^`abcdefghijklmnyz{|}~ PowerPoint Document(DocumentSummaryInformation8՜.+,D՜.+,@    On-screen ShowĴýy ArialTahoma Wingdings Courier NewTimes New RomanSymbol Mountain TopSlide 1Slide 2Slide 3Slide 4